Solvent and stereoelectronic effects on the solvolysis rates of oxaspirocyclopropanated 1-norbornyl triflates and related bridgehead derivatives - García Martínez, A.; De La Moya Cerero, S.; Teso Vilar, E.; García Fraile, A.; Lora Maroto, B.; Díaz Morillo, C. (Journal of Organic Chemistry, 2008)

Unexpected reactivity of 1-amine-2-methylenenorbornane hydrochlorides with m-CPBA - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; de la Moya Cerero, S.; Ruiz, P.M.; Morillo, C.D.; Maroto, B.L. (Tetrahedron Letters, 2007)

A new type of anomalous ozonolysis in strained allylic bicycloalkan-1-ols - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Letters, 2005)

Palladium(II)-catalyzed ring expansion of a 1-alkenyl cyclopentanol - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Letters, 2005)

Understanding the catalytic role of flexible chiral ?-amino alcohols: The 1-(2-aminoethyl)norbornan-2-ol model - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; De La Moya Cerero, S.; Maroto, B.L. (Tetrahedron, 2005)

Intramolecular-activation evidence for the unexpected Beckmann fragmentation of C(1)-substituted-7-bromonorbornane-2-ones - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron, 2004)

2-exo- versus 2-endo-Hydroxyl in ?-amino norbornan-2-ol-based catalysts: Investigating the role of the C(2) configuration in the asymmetric induction - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2004)

Synthesis and catalytic activity of 10-(aminomethyl)isoborneol-based catalysts: The role of the C(2)-group on the asymmetric induction - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2003)

First access to enantiopure C(7)-substituted fenchones: New norbornane-based chiral materials from the chiral pool - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2003)

C(10)-substituted camphors and fenchones by electrophilic treatment of 2-methylenenorbornan-1-ols: Enantiospecificity, scope, and limitations - De la Moya Cerero, S.; Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; Maroto, B.L. (Journal of Organic Chemistry, 2003)

Synthesis of 7-anti-bromo-3,3-dimethyl-2-oxonorbornane-1-carboxylic acid: A new chiral source from the chiral pool - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2002)

A new enantiospecific synthetic procedure to the taxoid-intermediate 10-methylenecamphor, and 10-methylenefenchone - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2002)

Straightforward synthesis of (1S)-10-dimethylaminomethylcamphor: An enantiospecific model procedure to C10-C-substituted camphor-derived chiral sources - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Letters, 2002)

A novel enantiospecific route to 10-hydroxyfenchone: A convenient intermediate for C(10)-O-substituted fenchones - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2002)

Unexpected hydrolysis of a C(7)-oxo-substituted 2-oxonorborn-1-yl triflate: Norbornane-ring expansion versus norbornane-ring contraction - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; Lora Maroto, B. (European Journal of Organic Chemistry, 2002)

Unexpected bromine-assisted Beckmann fragmentation of a C1-electron-acceptor substituted 7-bromonorbornan-2-one upon hydroxylamine treatment - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (European Journal of Organic Chemistry, 2002)

Chemoselective reaction of spiro[oxirane-2,2?-norborn]-1?-yl triflates with nucleophiles: A new case of HSAB-principle dependence - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B.; Díaz Morillo, C. (Tetrahedron Letters, 2001)

From natural camphor to (1R,2S)-2-chloromethyl-3-oxocyclopentanecarboxylic acid: A stereocontrolled approach to enantiopure sarkomycin - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; De Oro Osuna, S.; Lora Maroto, B. (Tetrahedron Letters, 2001)

First efficient preparation of enantiopure 10-bromofenchone: The key intermediate to C10-substituted fenchone-derived chiral sources - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Letters, 2001)

A new convenient procedure for the preparation of enantiopure C10-S- and C10-Se-substituted camphor-derived sulfides and selenides - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Letters, 2001)

A novel route to enantiopure cyclopentene carboxylic acids based on 3-endo-bromocamphor - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2001)

A new straightforward preparation of enantiopure 10-hydroxycamphor - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Lora Maroto, B. (Tetrahedron Asymmetry, 2000)

Erratum: A new highly efficient synthetic route to enantiopure 10-bromocamphor (Tetrahedron: Asymmetry 11 (2000) (3059) PII: S0957416600002792) - Maroto, B.L.; De La Moya Cerero, S.; García Martínez, A.; García Fraile, A.; Vilar, E.T. (Tetrahedron Asymmetry, 2000)

A new highly efficient synthetic route to enantiopure 10-bromocamphor - Maroto, B.L.; De La Moya Cerero, S.; Martínez, A.G.; Fraile, A.G.; Vilar, E.T. (Tetrahedron Asymmetry, 2000)

Electron ionization mass spectral studies of bridgehead 7,7-dimethylnorbornane-based ?-amino alcohols - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Martínez-Álvarez, R.; De La Mayo Cerero, S.; Martínez-Ruiz, P. (Rapid Communications in Mass Spectrometry, 2005)

An improved modification of ritter reaction - García Martínez, A.; Martínez Alvarez, R.; Teso Vilar, E.; García Fraile, A.; Hanack, M.; Subramanian, L.R. (Tetrahedron Letters, 1989)

Reduktive Arylierung von Vinyl?trifluoromethansulfonaten durch Friedel?Crafts?Reaktion - García Martínez, A.; Martínez Alvarez, R.; García Fraile, A.; Hanack, M.; Subramanian, L.R. (Chemische Berichte, 1987)

Electron ionization-induced fragmentation of bridgehead-substituted norbornan-2-ones derived from fenchone - Teso Vilar, E.; García Martínez, A.; García Fraile, A.; De La Moya Cerero, S.; Martínez-Ruiz, P.; Moreno Jiménez, F. (International Journal of Mass Spectrometry, 2013)

Electron ionization mass spectral studies of bridgeheadsubstituted norbornan-2-ones: Camphor derivatives - Vilar, E.T.; Fraile, A.G.; Cerero, S.D.L.M.; Martínez-Ruiz, P.; Jiménez, F.M. (Rapid Communications in Mass Spectrometry, 2011)

The role of conformational flexibility on the catalytic activity of norbornane-derived ?-, ?- and ?-amino alcohols - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; de la Moya Cerero, S.; Martínez Ruiz, P.; Díaz Morillo, C. (Tetrahedron Asymmetry, 2007)

Density functional theory study of self-association of N-methylformamide and its effect on intramolecular and intermolecular geometrical parameters and the cis/trans population - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Martínez-Ruiz, P. (Journal of Chemical Physics, 2006)

Stereocontrolled synthesis of conformationally restricted enantiopure triols and dihydroxy acids based on the norbornane framework - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Martínez-Ruiz, P. (Tetrahedron Asymmetry, 2005)

About the Leuckart reaction of chiral 2-norbornanones bearing electron-withdrawing groups: Reaction of bridgehead triflates and triflamides - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Martínez-Ruiz, P. (Tetrahedron, 2003)

The role of the substitution pattern on the catalytic activity of chiral bridgehead norbornane-derived ?-amino alcohols - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De la Moya Cerero, S.; Martínez-Ruiz, P. (Tetrahedron Asymmetry, 2002)

A computational and experimental study on the relative stabilities of cis and trans isomers of N-alkylamides in gas phase and in solution - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; Martínez-Ruiz, P. (Journal of Physical Chemistry A, 2002)

Bridgehead-norbornane-derived ?-amino alcohol catalysts: Structural factors influencing the chirality transfer - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De Moya Cerero, S.; Martínez-Ruiz, P.; Chicharro Villas, P. (Tetrahedron Asymmetry, 2002)

Enantioselective synthesis of both enantiomers of vicinal norbornanediamines through the Leuckart reaction of 2-norbornanones - Martínez, A.G.; Teso Vilar, E.; Fraile, A.G.; Martínez-Ruiz, P. (Tetrahedron Asymmetry, 2001)

Influence of the bridgehead substituent on the stereoselective Leuckart reaction of 2-norbornanones - Skeletal rearrangement versus structural retention - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Martínez-Ruiz, P. (European Journal of Organic Chemistry, 2001)

On the mechanism of the Leuckart reaction. Enantiospecific preparation of (1R,2R)- and (1S,2S)-N-(3,3-dimethyl-2-formylamino-1-norbornyl)acetamide - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Martínez Ruiz, P.; Macías San Antonio, R.; Martínez Alcázar, M.P. (Tetrahedron Asymmetry, 1999)

Electron impact fragmentation patterns of 3,3-dimethyl-1,2-norbornane derivatives - García Martínez, A.; Vilar, E.T.; García Fraile, A.; De La Moya Cerero, S.; Martínez Ruiz, P. (Rapid Communications in Mass Spectrometry, 1999)

Synthesis of enantiopure norbomane derivatives. Effect of bridgehead substituent on the ?-facial selectivity of the reduction of 2-norbomanones and their oximes - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Martínez Ruiz, P. (Tetrahedron Asymmetry, 1998)

Synthesis of homochiral 3-substituted cyclopentanones from 2-norbornanones - Martínez, A.G.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Martínez Ruiz, P.; Subramanian, L.R. (Tetrahedron Asymmetry, 1996)

Water-trapping of unstable carbocations taking place into the inverted region of the Marcus equation. First experimental and computational evidence - Martínez, A.G.; De La Moya Cerero, S.; Teso Vilar, E.; García Fraile, A. (Tetrahedron, 2012)

Stereoelectronic control in the solvolysis of spiroepoxidic 1-norbornyl triflates: Unexpected reactivity in 3-bromomethyl derivatives - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; Cerero, S.D.L.M.; Morillo, C.D. (Tetrahedron Letters, 2011)

The role of the C(2) configuration and methyl substitution on the catalytic activity of novel 2,3,3- and 2,7,7-trimethyl-substituted ?- aminonorbornan-2-ols - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; De La Moya Cerero, S.; Ruiz, P.M.; Morillo, C.D. (Chirality, 2010)

Surprising obtention of an enantiopure eight-membered cyclic ether from camphor - García Martínez, A.; Vilar, E.T.; Fraile, A.G.; de la Moya Cerero, S.; Morillo, C.D. (Tetrahedron Letters, 2007)

First efficient synthesis of enantiopure homoketopinic acid - Martínez, A.G.; de la Moya Cerero, S.; Teso Vilar, E.; García Fraile, A.; Díaz Morillo, C.; de las Casas Engel, T. (Letters in Organic Chemistry, 2007)

Enantiospecific access to 10-N-substituted camphors - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; De La Moya Cerero, S.; Díaz Morillo, C. (Tetrahedron, 2005)

Enantiospecific access to various C(9),C(10)-disubstituted camphors: Scope and limitations - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; De La Moya Cerero, S.; Morillo, C.D.; Morillo, R.P. (Journal of Organic Chemistry, 2004)

Self-recognition and hydrogen bonding by polycyclic bridgehead monoalcohols - Fraile, A.G.; Morris, D.G.; Martínez, A.G.; De La Moya Cerero, S.; Muir, K.W.; Ryder, K.S.; Vilar, E.T. (Organic and Biomolecular Chemistry, 2003)

About the timing of Wagner-Meerwein and Nametkin rearrangements, 6,2- hydride shift, proton elimination and cation trapping in 2-norbornyl carbocations - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; Fernández, A.H.; De La Moya Cerero, S.; Jiménez, F.M. (Tetrahedron, 1998)

Synthesis of methyl (1R,2S)-?,?-dimethyl-3-oxo-2-pentylcyclopentaneacetate. A model procedure for the preparation of chiral jasmonoids and prostaglandins - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; De La Moya Cerero, S.; Ruiz, P.M.; Álvarez, P.P.G. (Tetrahedron Asymmetry, 1997)

A facile synthesis of new homochiral ?-amino alcohols with norbornane framework - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; De La Moya Cerero, S.; Ruiz, P.M.; Subramanian, L.R. (Tetrahedron Asymmetry, 1996)

Erratum: Synthesis of substituted 1-norbornylamines with antiviral activity (Journal of Medicinal Chemistry (1995) 38 (4474-4475)) - Martinez, A.G.; Vilar, E.T.; Fraile, A.G.; Cerero, S.D.L.M.; Herrero, M.E.R.; Ruiz, P.M.; Subramanian, L.R.; Gancedo, A.G. (Journal of Medicinal Chemistry, 1996)

A new entry to homochiral bridgehead 1-acyl and 1-hydroxyalkyl bicyclo[21.1]hexanes - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; De La Moya Cerero, S.; Subramanian, L.R. (Synlett, 1994)

Synthesis of homochiral 1,2-diols from (-)-fenchone and (+)-camphor - García6Martïnez, A.; Teso Vilar, E.; Fraile, A.G.; de la Moya Cerero, S.; Subramanian, L.R. (Tetrahedron: Asymmetry, 1994)

A facile synthesis of homochiral 1-norbornanecarboxylic acids and 1-norbornanecarbonitriles - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; de la Moya Cerero, S.; de Diego, J.M.G.-F.; Subramanian, L.R. (Tetrahedron: Asymmetry, 1994)

Synthesis of homochiral cyclopentane derivatives by Beckmann fragmentation of 1-substituted 2-norbornanones - Martínez, A.G.; Vilar, E.T.; García Fraile, A.; de la Moya Cerero, S.; Oliva, C.D.; Subramanian, L.R.; Maichle, C. (Tetrahedron: Asymmetry, 1994)

A new procedure for formylation of less active aromatics - Martínez, A.G.; Alvarez, R.M.; Barcina, J.O.; De La Moya Cerero, S.; Vilar, E.T.; Fraile, A.G.; Hanack, M.; Subramanian, L.R. (Journal of the Chemical Society, Chemical Communications, 1990)

Selectivity in the reactions of less stable carbocations with magnesium halides in aprotic solvents. A theoretical approach to the constant selectivity principle - Martínez, A.G.; Alvarez, R.M.; Teso Vilar, E.; García Fraile, A.; Osío Barcina, J.; Subramanían, L.R. (Tetrahedron, 1995)

Unusual reactivity of norbornane bridgehead derivatives - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Osío Barcina, J.; Hanack, M.; Subramanian, L.R. (Tetrahedron Letters, 1989)

Fragmentation of vinyl triflates by electron impact. Mechanism of an unusual double hydrogen atom transfer reaction - Martínez, A.G.; Fernández, A.H.; Alvarez, R.M.; Barcina, J.O.; Vilar, E.T.; Fraile, A.G.; Subramanian, L.R.; Märkl, R.; Hanack, M. (Rapid Communications in Mass Spectrometry, 1994)

Synthesis of Substituted 1-Norbornylamines with Antiviral Activity - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; de la Cerero, S.M.; Herrero, M.E.R.; Ruiz, P.M.; Subramanian, L.R.; Gancedo, A.G. (Journal of Medicinal Chemistry, 1995)

Enantiospecific Synthesis of 9,10-Dihalocamphors - García Martínez, A.; Teso Vilar, E.; García Fraile, A.; Moya De La Cerero, S.; Díaz Morillo, C.; Pérez Morillo, R. (Synlett, 2004)

Herstellung von Vinyl-iodiden durch Umsetzung von Vinyl-triflaten mit Magnesiumiodid - García Martínez, A.; Martínez Alvarez, R.; García Fraile, A.; Subramanian, L.R.; Hanack, M. (Synthesis (Germany), 1986)

Synthesis of Bridgehead Derivatives; 1. Preparation of Substituted Bicyelo[2.2.1]heptan-l-ols and the Corresponding Trifluoromethanesul-fonates - Martínez, A.G.; Vilar, E.T.; Fraile, A.G.; Franco, C.R.; Salvador, J.S.; Subramanian, L.R.; Hanack, M. (Synthesis (Germany), 1987)

Preparation of alkyl- and phenyl-substituted pyrimidines - Martínez, A.G.; Fernández, A.H.; Alvarez, R.M.; Vilar, E.T.; Fraile, A.G.; Barcina, J.O.; Iglesias, L.P. (Tetrahedron Letters, 1987)

Eine einfache methode zur darstellung tertiärer iodide - Martínez, A.G.; Alvarez, R.M.; Vilar, E.T.; Fraile, A.G.; Barcina, J.O.; Hanack, M.; Subramanianb, L.R. (Tetrahedron Letters, 1987)

Ungewöhnliche Reaktivität gespannter Brückenkopfderivate - Martínez, A.G.; Fraile, A.G. (Chemische Berichte, 1983)

Notizen. Sterisch gesteuerte Reaktionswege von substituierten 2?Norbornyl?Kationen - Martínez, A.G.; Fraile, A.G.; García, J.M.S. (Chemische Berichte, 1983)